Phosphoric and carboxylic methacrylate esters as bonding agents in self-adhesive resin cements

Liu,Wenshu; Meng,Hongmei; Sun,Zhiguang; Jiang,Riwen; Dong,Chang‑An; Zhang,Congxiao

doi:10.3892/etm.2018.5937

Phosphoric and carboxylic methacrylate esters as bonding agents in self-adhesive resin cements

Authors:
- Wenshu Liu
- Hongmei Meng
- Zhiguang Sun
- Riwen Jiang
- Chang‑An Dong
- Congxiao Zhang
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Affiliations: Department of Stomatology, The First Hospital of Jilin University, Changchun, Jilin 130021, P.R. China, Department of Neurology, The First Hospital of Jilin University, Changchun, Jilin 130021, P.R. China, Department of Stomatology, Jilin Province Hospital, Changchun, Jilin 130021, P.R. China, Department of Stomatology, 461 Outpatient Department, 208 Military Hospital, Changchun, Jilin 130021, P.R. China, Department of Endodontics, Bai‑He Stomatological Hospital, Changchun, Jilin 130041, P.R. China
Published online on: March 8, 2018 https://doi.org/10.3892/etm.2018.5937
Pages: 4531-4537

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Abstract

The aim of the present study was to investigate the effect of pH and phosphoric ester structure (phosphonate or phosphate) on the bond strength of different dental restorative materials. The following three self‑adhesive resin cements were used in the present study: RelyX™ Unicem, Maxcem and Multilink Sprint The pH of each cement was measured using a pH meter. The cements were used to attach a variety of restorative materials to human dentin and the bond strength was measured by assessing shear strength using a universal testing machine. The pH values of RelyX Unicem, Maxcem and Multilink Sprint were 3.78, 1.78 and 3.42, respectively. Maxcem, a phosphate‑based self‑adhesive cement, was demonstrated to form the weakest bonds. No significant difference in bond strength was observed between RelyX Unicem and Multilink Sprint, which are phosphonate‑based cements. The results of the present study suggest that the chemical structure of the functional monomer influences the performance of an adhesive material. Furthermore, the pH of acidic functional monomers containing phosphonate or phosphate groups has an effect on the strength of bonds formed between dentin and restorative materials.

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